Asymmetric Synthesis

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Chiral Catalysts, Fine Chemistry, Ligands and Reagents
(11aS)-3 – 7-Bis((4-(1 – 1-dimethylethyl)phenyl)-10 – 11 – 12 – 13-tetrahydro-5-hydroxy-diindeno[7 – 1-de:1′ – 7′-fg][1 – 3 – 2]dioxaphosphocin
$904.96 – $1,374.74

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Chiral Catalysts, Fine Chemistry, Ligands and Reagents
(11aS)-3 – 7-Bis([1 – 1′-biphenyl]-4-yl)-10 – 11 – 12 – 13-tetrahydro-5-hydroxy-diindeno[7 – 1-de:1′ – 7′-fg][1 – 3 – 2]dioxaphosphocin
$810.34 – $1,157.41

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Chiral Catalysts, Fine Chemistry, Ligands and Reagents
(11aS)-3 – 7-Bis(1-pyrenyl)-10 – 11 – 12 – 13-tetrahydro-5-hydroxy-diindeno[7 – 1-de:1′ – 7′-fg][1 – 3 – 2]dioxaphosphocin
$1,154.59 – $1,641.06

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Chiral Catalysts, Fine Chemistry, Ligands and Reagents
(11aS)-3 – 7-Bis(3 – 5-dichlorophenyl)-10 – 11 – 12 – 13-tetrahydro-5-hydroxy-5-oxide-diindeno[7 – 1-de:1′ – 7′-fg][1 – 3 – 2]dioxaphosphocin
$1,305.60

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Chiral Catalysts, Fine Chemistry, Ligands and Reagents
(11aS)-3 – 7-Bis(4-(trifluoromethyl)phenyl)-10 – 11 – 12 – 13-tetrahydro-5-hydroxy-5-oxide-diindeno[7 – 1-de:1′ – 7′-fg][1 – 3 – 2]dioxaphosphocin
$1,224.00

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Chiral Catalysts, Fine Chemistry, Ligands and Reagents
(11aS)-3 – 7-Bis(4-chlorophenyl)-10 – 11 – 12 – 13-tetrahydro-5-hydroxy-diindeno[7 – 1-de:1′ – 7′-fg][1 – 3 – 2]dioxaphosphocin
$1,053.71

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Chiral Catalysts, Fine Chemistry, Ligands and Reagents
(11aS)-3 – 7-Bis(4-methoxyphenyl)-10 – 11 – 12 – 13-tetrahydro-5-hydroxy-5-oxide-diindeno[7 – 1-de:1′ – 7′-fg][1 – 3 – 2]dioxaphosphocin
$1,175.26

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Chiral Catalysts, Fine Chemistry, Ligands and Reagents
(11aS)-3 – 7-Bis(4-nitrophenyl)-10 – 11 – 12 – 13-tetrahydro-5-hydroxy-5-oxide-diindeno[7 – 1-de:1′ – 7′-fg][1 – 3 – 2]dioxaphosphocin
$1,048.34

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Chiral Catalysts, Fine Chemistry, Ligands and Reagents
(11aS)-3 – 7-Bis(triphenylsilyl)-10 – 11 – 12 – 13-tetrahydro-5-hydroxy-5-oxide-diindeno[7 – 1-de:1′ – 7′-fg][1 – 3 – 2]dioxaphosphocin
$918.00

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Chiral Catalysts, Fine Chemistry, Ligands and Reagents
(11aS)-3 – 7-Bis[3 – 5-bis(tert-butyl)-4-methoxyphenyl]-10 – 11 – 12 – 13-tetrahydro-5-hydroxy-5-oxide-diindeno[7 – 1-de:1′ – 7′-fg][1 – 3 – 2]dioxaphosphocin
$856.80

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Chiral Catalysts, Fine Chemistry, Ligands and Reagents
(11aS)-3 – 7-Bis[3 – 5-bis(trifluoromethyl)phenyl]-10 – 11 – 12 – 13-tetrahydro-5-hydroxy-5-oxide-diindeno[7 – 1-de:1′ – 7′-fg][1 – 3 – 2]dioxaphosphocin
$428.11 – $1,243.84

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Chiral Catalysts, Fine Chemistry, Ligands and Reagents
(11aS)-3 – 7-Bis[4-(2-naphthalenyl)phenyl]-10 – 11 – 12 – 13-tetrahydro-5-hydroxy-diindeno[7 – 1-de:1′ – 7′-fg][1 – 3 – 2]dioxaphosphocin
$1,030.20

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Chiral Catalysts, Fine Chemistry, Ligands and Reagents
(11aS)-3 – 7-Di-9-anthracenyl-10 – 11 – 12 – 13-tetrahydro-5-hydroxy-5-oxide-diindeno[7 – 1-de:1′ – 7′-fg][1 – 3 – 2]dioxaphosphocin
$947.46 – $1,353.76

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Chiral Catalysts, Fine Chemistry, Ligands and Reagents
(11bR – 11’bR)-4 – 4′-[(1S – 2S)-1 – 2-Diphenyl-1 – 2-ethanediyl]bis[4 – 5-dihydro-3H-dinaphth[2 – 1-c:1′ – 2′-e]azepine
$491.30

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Chiral Catalysts, Fine Chemistry, Ligands and Reagents
(11bR)-2 – 6-Bis([1 – 1′-biphenyl]-4-yl)-4-hydroxy-4-oxide-dinaphtho[2 – 1-d:1′ – 2′-f][1 – 3 – 2]dioxaphosphepin
$148.75

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Chiral Catalysts, Fine Chemistry, Ligands and Reagents
(11bR)-2 – 6-Bis([1 – 1′-biphenyl]-4-yl)-8 – 9 – 10 – 11 – 12 – 13 – 14 – 15-octahydro-4-hydroxy-4-oxide-dinaphtho[2 – 1-d:1′ – 2′-f][1 – 3 – 2]dioxaphosphepin
$118.71 – $822.80

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Chiral Catalysts, Fine Chemistry, Ligands and Reagents
(11bR)-2 – 6-Bis(3 – 5-dichlorophenyl)-4-hydroxy-4-oxide-dinaphtho[2 – 1-d:1′ – 2′-f][1 – 3 – 2]dioxaphosphepin
$177.09

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Chiral Catalysts, Fine Chemistry, Ligands and Reagents
(11bR)-2 – 6-Bis(3 – 5-dimethylphenyl)-4-hydroxy-4-oxide-dinaphtho[2 – 1-d:1′ – 2′-f][1 – 3 – 2]dioxaphosphepin
$85.85

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Asymmetric Synthesis

(11aS)-3 – 7-Bis((4-(1 – 1-dimethylethyl)phenyl)-10 – 11 – 12 – 13-tetrahydro-5-hydroxy-diindeno[7 – 1-de:1′ – 7′-fg][1 – 3 – 2]dioxaphosphocin

(11aS)-3 – 7-Bis([1 – 1′-biphenyl]-4-yl)-10 – 11 – 12 – 13-tetrahydro-5-hydroxy-diindeno[7 – 1-de:1′ – 7′-fg][1 – 3 – 2]dioxaphosphocin

(11aS)-3 – 7-Bis(1-pyrenyl)-10 – 11 – 12 – 13-tetrahydro-5-hydroxy-diindeno[7 – 1-de:1′ – 7′-fg][1 – 3 – 2]dioxaphosphocin

(11aS)-3 – 7-Bis(3 – 5-dichlorophenyl)-10 – 11 – 12 – 13-tetrahydro-5-hydroxy-5-oxide-diindeno[7 – 1-de:1′ – 7′-fg][1 – 3 – 2]dioxaphosphocin

(11aS)-3 – 7-Bis(4-(trifluoromethyl)phenyl)-10 – 11 – 12 – 13-tetrahydro-5-hydroxy-5-oxide-diindeno[7 – 1-de:1′ – 7′-fg][1 – 3 – 2]dioxaphosphocin

(11aS)-3 – 7-Bis(4-chlorophenyl)-10 – 11 – 12 – 13-tetrahydro-5-hydroxy-diindeno[7 – 1-de:1′ – 7′-fg][1 – 3 – 2]dioxaphosphocin

(11aS)-3 – 7-Bis(4-methoxyphenyl)-10 – 11 – 12 – 13-tetrahydro-5-hydroxy-5-oxide-diindeno[7 – 1-de:1′ – 7′-fg][1 – 3 – 2]dioxaphosphocin

(11aS)-3 – 7-Bis(4-nitrophenyl)-10 – 11 – 12 – 13-tetrahydro-5-hydroxy-5-oxide-diindeno[7 – 1-de:1′ – 7′-fg][1 – 3 – 2]dioxaphosphocin

(11aS)-3 – 7-Bis(triphenylsilyl)-10 – 11 – 12 – 13-tetrahydro-5-hydroxy-5-oxide-diindeno[7 – 1-de:1′ – 7′-fg][1 – 3 – 2]dioxaphosphocin

(11aS)-3 – 7-Bis[3 – 5-bis(tert-butyl)-4-methoxyphenyl]-10 – 11 – 12 – 13-tetrahydro-5-hydroxy-5-oxide-diindeno[7 – 1-de:1′ – 7′-fg][1 – 3 – 2]dioxaphosphocin

(11aS)-3 – 7-Bis[3 – 5-bis(trifluoromethyl)phenyl]-10 – 11 – 12 – 13-tetrahydro-5-hydroxy-5-oxide-diindeno[7 – 1-de:1′ – 7′-fg][1 – 3 – 2]dioxaphosphocin

(11aS)-3 – 7-Bis[4-(2-naphthalenyl)phenyl]-10 – 11 – 12 – 13-tetrahydro-5-hydroxy-diindeno[7 – 1-de:1′ – 7′-fg][1 – 3 – 2]dioxaphosphocin

(11aS)-3 – 7-Di-9-anthracenyl-10 – 11 – 12 – 13-tetrahydro-5-hydroxy-5-oxide-diindeno[7 – 1-de:1′ – 7′-fg][1 – 3 – 2]dioxaphosphocin

(11bR – 11’bR)-4 – 4′-[(1S – 2S)-1 – 2-Diphenyl-1 – 2-ethanediyl]bis[4 – 5-dihydro-3H-dinaphth[2 – 1-c:1′ – 2′-e]azepine

(11bR)-2 – 6-Bis([1 – 1′-biphenyl]-4-yl)-4-hydroxy-4-oxide-dinaphtho[2 – 1-d:1′ – 2′-f][1 – 3 – 2]dioxaphosphepin

(11bR)-2 – 6-Bis([1 – 1′-biphenyl]-4-yl)-8 – 9 – 10 – 11 – 12 – 13 – 14 – 15-octahydro-4-hydroxy-4-oxide-dinaphtho[2 – 1-d:1′ – 2′-f][1 – 3 – 2]dioxaphosphepin

(11bR)-2 – 6-Bis(3 – 5-dichlorophenyl)-4-hydroxy-4-oxide-dinaphtho[2 – 1-d:1′ – 2′-f][1 – 3 – 2]dioxaphosphepin

(11bR)-2 – 6-Bis(3 – 5-dimethylphenyl)-4-hydroxy-4-oxide-dinaphtho[2 – 1-d:1′ – 2′-f][1 – 3 – 2]dioxaphosphepin